Smith教授等編著的《化工熱力學(xué)導(dǎo)論》是世界化工領(lǐng)域影響最大、發(fā)行范圍最廣的化工熱力學(xué)教材。本書是根據(jù)英文原版書《化工熱力學(xué)導(dǎo)論》第7版改編。
改編書選取了原書前13章，內(nèi)容涵蓋了化學(xué)工程師專業(yè)教育所必需的內(nèi)容。全書主要內(nèi)容包括以下幾個(gè)方面：熱力學(xué)基本概念和基本定律、純流體的PVT性質(zhì)、熱效應(yīng)、純流體的熱力學(xué)性質(zhì)、熱力學(xué)在流動(dòng)過程中的應(yīng)用、熱力做功、制冷、汽液平衡、溶液熱力學(xué)理論和應(yīng)用以及化學(xué)反應(yīng)平衡。這13章內(nèi)容可以分為三部分：熱力學(xué)和化學(xué)熱力學(xué)基礎(chǔ)，包括第1-6章；熱力學(xué)在工業(yè)過程中的應(yīng)用，包括第7-9章；熱力學(xué)在化學(xué)過程中的應(yīng)用，包括第10-13章。書中給出了大量既有理論意義，又切合工業(yè)實(shí)際的例題，并配有大量來自工業(yè)實(shí)踐的習(xí)題。
全書行文流暢、圖表豐富、通俗易懂。可作為化學(xué)工程與工藝專業(yè)以及其他相關(guān)專業(yè)的化工熱力學(xué)教科書，也可以作為相關(guān)專業(yè)研究人員，工程設(shè)計(jì)和生產(chǎn)管理技術(shù)人員的重要參考書，也可以用作化工專業(yè)英語的教材或選讀材料。
江振西，ZhenxiJiang，鄭州大學(xué)教授。1954年7月生于河北省磁縣。1975年入鄭州工學(xué)院（現(xiàn)鄭州大學(xué)）化工系就讀無機(jī)化工專業(yè)。1978年考入新鄉(xiāng)師范學(xué)院（現(xiàn)河南師范大學(xué)）化學(xué)系物理化學(xué)專業(yè)。1981年畢業(yè)于新鄉(xiāng)師范學(xué)院，獲研究生畢業(yè)證書，1982年獲武漢大學(xué)理學(xué)碩士學(xué)位。1982年3月起在鄭州工學(xué)院任教，主教化工熱力學(xué)等課程。1989年獲中國政府、包玉剛基金會(huì)和英國政府共同設(shè)立的中英友好獎(jiǎng)學(xué)金赴英國利茲大學(xué)訪問研究。1990年獲英國海外留學(xué)生獎(jiǎng)學(xué)金和利茲大學(xué)Tetley and Lupton 獎(jiǎng)學(xué)金讀博士學(xué)位，1994年獲利茲大學(xué)哲學(xué)博士學(xué)位。之后繼續(xù)在利茲大學(xué)從事研究工作。2006年開始，在鄭州大學(xué)教授化工熱力學(xué)（雙語）課程、研究生專業(yè)英語和研究生高等化工熱力學(xué)（全英語）等課程。
List of Symbols
Preface
Chapter 1 Introduction1
1.1 THE SCOPE OF THERMODYNAMICS1
1.2 DIMENSIONS AND UNITS2
1.3 MEASURES OF AMOUNT OR SIZE2
1.4 FORCE3
1.5 TEMPERATURE4
1.6 PRESSURE6
1.7 WORK8
1.8 ENERGY9
1.9 HEAT14
KEY NOTES15
GLOSSARY AND EXPLANATIONS17 List of Symbols
Preface
Chapter 1 Introduction1
1.1 THE SCOPE OF THERMODYNAMICS1
1.2 DIMENSIONS AND UNITS2
1.3 MEASURES OF AMOUNT OR SIZE2
1.4 FORCE3
1.5 TEMPERATURE4
1.6 PRESSURE6
1.7 WORK8
1.8 ENERGY9
1.9 HEAT14
KEY NOTES15
GLOSSARY AND EXPLANATIONS17
CONCEPTUAL PROBLEMS27
PROBLEMS28
Chapter 2 The First Law and Other Basic Concepts33
2.1 JOULE’S EXPERIMENTS33
2.2 INTERNAL ENERGY33
2.3 THE FIRST LAW OF THERMODYNAMICS34
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS35
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS37
2.6 EQUILIBRIUM40
2.7 THE PHASE RULE41
2.8 THE REVERSIBLE PROCESS43
2.9 CONSTANT-V AND CONSTANT-P PROCESSES48
2.10 ENTHALPY49
2.11 HEAT CAPACITY51
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS55
KEY NOTES65
GLOSSARY AND EXPLANATIONS68
CONCEPTUAL PROBLEMS84
PROBLEMS85
Chapter 3 Volumetric Properties of Pure Fluids93
3.1 PVT BEHAVIOR OF PURE SUBSTANCES93
3.2 VIRIAL EQUATIONS OF STATE98
3.3 THE IDEAL GAS101
3.4 APPLICATION OF THE VIRIAL EQUATIONS113
3.5 CUBIC EQUATIONS OF STATE117
3.6 GENERALIZED CORRELATIONS FOR GASES126
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS134
KEY NOTES136
GLOSSARY AND EXPLAINATIONS140
CONCEPTUAL PROBLEMS147
PROBLEMS149
Chapter 4 Heat Effects162
4.1 SENSIBLE HEAT EFFECTS162
4.2 LATENT HEATS OF PURE SUBSTANCES169
4.3 STANDARD HEAT OF REACTION171
4.4 STANDARD HEAT OF FORMATION173
4.5 STANDARD HEAT OF COMBUSTION176
4.6 TEMPERATURE DEPENDENCE OF ΔH 176
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS179
KEY NOTES187
GLOSSARY AND EXPLAINATIONS187
CONCEPTUAL PROBLEMS193
PROBLEMS194
Chapter 5 The Second Law of Thermodynamics202
5.1 STATEMENTS OF THE SECOND LAW202
5.2 HEAT ENGINES203
5.3 THERMODYNAMIC TEMPERATURE SCALES206
5.4 ENTROPY209
5.5 ENTROPY CHANGES OF AN IDEAL GAS212
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW215
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS217
5.8 CALCULATION OF IDEAL WORK222
5.9 LOST WORK226
5.10 THE THIRD LAW OF THERMODYNAMICS229
KEY NOTES230
GLOSSARY AND EXPLAINATIONS231
CONCEPTUAL PROBLEMS237
PROBLEMS239
Chapter 6 Thermodynamic Properties of Fluids247
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES247
6.2 RESIDUAL PROPERTIES256
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE263
6.4 TWO-PHASE SYSTEMS268
6.5 THERMODYNAMIC DIAGRAMS273
6.6 TABLES OF THERMODYNAMIC PROPERTIES274
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES278
KEY NOTES287
GLOSSARY AND EXPLAINATIONS288
CONCEPTUAL PROBLEMS293
PROBLEMS295
Chapter 7 Applications of Thermodynamics to Flow Processes308
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS309
7.2 TURBINES (EXPANDERS)321
7.3 COMPRESSION PROCESSES327
KEY NOTES333
GLOSSARY AND EXPLAINATIONS335
CONCEPTUAL PROBLEMS340
PROBLEMS342
Chapter 8 Production of Power from Heat352
8.1 THE STEAM POWER PLANT353
8.2 INTERNAL-COMBUSTION ENGINES363
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES371
KEY NOTES373
GLOSSARY AND EXPLAINATIONS374
CONCEPTUAL PROBLEMS377
PROBLEMS379
Chapter 9 Refrigeration and Liquefaction384
9.1 THE CARNOT REFRIGERATOR384
9.2 THE VAPOR-COMPRESSION CYCLE385
9.3 THE CHOICE OF REFRIGERANT388
9.4 ABSORPTION REFRIGERATION390
9.5 THE HEAT PUMP392
9.6 LIQUEFACTION PROCESSES393
KEY NOTES398
GLOSSARY AND EXPLAINATIONS399
CONCEPTUAL PROBLEMS403
PROBLEMS404
Chapter 10 Vapor/Liquid Equilibrium: Introduction409
10.1 THE NATURE OF EQUILIBRIUM409
10.2 THE PHASE RULE; DUHEM’S THEOREM410
10.3 VLE: QUALITATIVE BEHAVIOR412
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM414
10.5 VLE BY MODIFIED RAOULT’S LAW423
10.6 VLE FROM K-VALUE CORRELATIONS428
KEY NOTES434
GLOSSARY AND EXPLAINATIONS435
CONCEPTUAL PROBLEMS442
PROBLEMS444
Chapter 11 Solution Thermodynamics: Theory452
11.1 FUNDAMENTAL PROPERTY RELATION452
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA454
11.3 PARTIAL PROPERTIES455
11.4 THE IDEAL-GAS MIXTURE MODEL466
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES469
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION475
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT481
11.8 THE IDEAL-SOLUTION MODEL485
11.9 EXCESS PROPERTIES487
KEY NOTES493
GLOSSARY AND EXPLAINATIONS496
CONCEPTUAL PROBLEMS501
PROBLEMS502
Chapter 12 Solution Thermodynamics: Applications512
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA512
12.2 MODELS FOR THE EXCESS GIBBS ENERGY527
12.3 PROPERTY CHANGES OF MIXING530
12.4 HEAT EFFECTS OF MIXING PROCESSES536
KEY NOTES548
GLOSSARY AND EXPLAINATIONS549
CONCEPTUAL PROBLEMS553
PROBLEMS555
Chapter 13 Chemical-Reaction Equilibria567
13.1 THE REACTION COORDINATE568
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS572
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT573
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT575
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS579
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION581
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS585
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS597
13.9 MULTIREACTION EQUILIBRIA601
KEY NOTES611
GLOSSARY AND EXPLAINATION613
CONCEPTUAL PROBLEMS617
PROBLEMS619
Appendix A Conversion Factors and Values of the Gas Constant630
Appendix B Properties of Pure Species632
Appendix C Heat Capacities ad Property Changes of Formation636
Appendix D Representative Computer Programs641
參考文獻(xiàn)651
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